Carcinogenic chemical material is said to be stored at the Chemie-Pack plant
Southern areas of the Netherlands are on the top state of alert after a blaze at a chemical plant near Rotterdam sent out a thick plume of smoke.
The cloud from the fire at Moerdijk was floating north and had reached the city of Dordrecht, Dutch media said.
Some 400,000 litres of carcinogenic material are stored at the Chemie-Pack plant, De Telegraaf says.
There were no reports of casualties and officials said it was unclear if toxic fumes had been released.
The flames were said to be up to 40m (131ft) high and there were reports of repeated, loud explosions.
Residents in Dordrecht were being warned to keep windows and doors shut.
Sarah Raymond, a BBC News website reader who lives in Dordrecht, said people in the area were frightened as they were unsure about any potential risks to their health.
"It is quite scary. The sky is thick with black smoke and we still don't know if it is toxic or not.
"There is a very unpleasant, chemical smell in the air. I could see the chemical site from my window at work this afternoon across the water and I only live two miles from there.
"But we have not been given any information from the authorities and there is no number to call to find out more. It is frightening."
The Dutch government set up a co-ordination centre for emergency services and southern areas of the province of South Holland were placed on their highest state of alert.
Chemie-Pack, which is about 40km (25 miles) south of the port of Rotterdam, processes and packs products for the chemical industry, the company says on its website.
All 50 Chemie-Pack staff were safe, according to local officials.
A Shell refinery in the Moerdijk industrial zone was not affected by the fire, a spokesman told Reuters news agency.
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